Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

نویسندگان

چکیده

Abstract Phase equilibrium data ( $$p$$ p , $$T$$ T $$y$$ y ) for the binary systems of carbon dioxide + dimethyl carbonate and ethyl methyl were obtained. All measured isotherms ranging from 298.2 K to 328.2 with pressure between 0.13 MPa 10.6 MPa. A static technique was established samples quantified using an offline method. The results modeled Peng–Robinson equation state van der Waals one-fluid mixing rules. Graphical

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Thermodynamic Simulation of Carbonate Cements-Water-Carbon Dioxide Equilibrium in Sandstone for Prediction of Precipitation/Dissolution of Carbonate Cements

Carbonate cements, such as calcite, dolomite, ferrocalcite and ankerite, play important roles in the formation of pores in sandstones: precipitation of carbonate cements modifies pores and inhibits compaction, while dissolution creates secondary pores. This work proposed a precipitation-dissolution model for carbonate cements-CO2-H2O system by means of ion equilibrium concentration ([M2+], M = ...

متن کامل

Gas-Phase Synthesis of Dimethyl Carbonate from Methanol and Carbon Dioxide Over Co1.5pw12o40 Keggin-Type Heteropolyanion

The reactivity of Co(1.5)PW(12)O(40) in the direct synthesis of dimethyl carbonate (DMC) from CO(2) and CH(3)OH was investigated. The synthesized catalyst has been characterized by means of FTIR, XRD, TG, and DTA and tested in gas phase under atmospheric pressure. The effects of the reaction temperature, time on stream, and methanol weight hourly space velocity (MWHSV) on the conversion and DMC...

متن کامل

Isobaric vapor-Liquid Equilibrium of Ethyl-Acetate+ 2-Propanol and Ethyl Acetate+ Ethanol Mixtures at 84.8 kPa

Accurate vapor-liquid equilibrium data have been obtained for ethyl acetate + 2-propanol and ethyl acetate + ethanol mixtures at 84.8 kPa, and the results are discussed thermodynamically. The vapor-liquid equilibrium data are correlated with redlich-Kister, Margules, Van-Laar and Ortega, equations the parameters and standard deviation of which are calculated and reported. The best correlati...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: International Journal of Thermophysics

سال: 2023

ISSN: ['1572-9567', '0195-928X']

DOI: https://doi.org/10.1007/s10765-023-03186-2